Record 31 times. Copa del Rey Winners Barcelona will meet Valencia in the quarter-finals, as determined by Monday’s draw.
Real Madrid, the Spanish and European Champions, travels to Leganes, while Atletico Madrid hosts Getafe in another capital rivalry.
Barcelona defeated Real Betis 5-1 in the last 16 to advance to the final eight, where they will meet Los Che in a rematch of the 2019 final, which Valencia won 2-1.
Real Sociedad welcome Osasuna in the other match, with the quarter-finals to be played between February 4-6.
Full draw
Valencia v Barcelona
Leganes v Real Madrid
Atletico Madrid v Getafe
Real Sociedad v Osasuna